wash and degrease them
sand with 600 sand paper
just spay light coats with rattle can
until it looks shiny
im not sure how hot the drums get
on the outside but get high temp
engine paint its the same price
if you have access to a sand blaster,you should use that.easy to get the old paint off and it preps the surface for you.
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Hmm. Sand it to 400 grit or so and wipe down with thinner. On that, I'd use a regular Krylon and tape off the tires; you'll never be able to lever on the tires again withour messing up the paint.
funny thing, i bought the 7$ a can "high performance wheel paint" and it would always wrinkle up, or fish-eye, i went and got the cheapest gloss black(2$ a can!), and it worked great, first time, it still looks good, no chips or anything!
i have had the best luck with powdercoating the wheels, simply because the wheels will be subjected to tire irons, multiple cleanings, road dirt and oil, wipe downs... etc.
i know it's somewhat expensive, but if you want to do it right, powdercoating is the only way to go.
either way, most definitely sandblast your wheels before doing anything to them - then prime them before painting. this will make your paint coat last much longer!
PM me if you need me to help ya get them sandblasted; i have an awesome sandblasting cabinet and a powdercoating resource.